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PBT注塑成型的工艺条件是什么
PBT的成型加工性能
1)PBT的吸湿性较小,但在高温下的水分比较敏感,成型加工时会使PBT分子降解,色泽变深,表面产生斑痕,故通常应进行干燥处理。
2)PBT熔料有极好的流动性,因此易于成型薄壁、形状复杂的制品,但要注意模具溢料,以及喷嘴流涎现象。
3)PBT有明显的熔点,当温度升至熔点以上时,流动性会猛然增加,尤要引起注意。
4)PBT成型加工范围较窄,冷却时结晶很快,加之流动性好,特别适于快速注射。
5)PBT了有较大的收缩率及其收缩范围,且在不同方向的收缩率差别较其他塑料更明显。
6)PBT对缺口、尖角的反应很敏感,在这些位置易出现应力集中,使承载能力大为下降,在受力或受冲击时易发生破裂,因此在设计塑件时应注意这一点,所有转角处,特别是内部转角应尽量采用圆弧过渡。
7)纯PBT的伸长率可达200%,因此带有较小凹陷的制品可以从模具上强制脱模。但用玻纤或填料填充后,其伸长率大为下降,在制品中如有凹陷就不能实施强制脱模。
8)PBT模具的流道在可能的情况下以短粗为佳,以圆流道效果最好。一般改性和未改性的PBT均可用普通流道,但玻纤增强PBT应用热流道成型才能有好效果。
9)点浇口和潜伏浇口的剪切作用大,能降低PBT熔料的表观粘度,有利于成型,是经常采用的浇口,浇口直径应以偏大为好。
10)浇口最好正对型芯腔或型芯,这样可以避免喷射,并使熔料在模腔中流动时回补最小。否则,制品容易产生表面缺陷,并使性能劣化。
PBT的主要注塑成型条件
1)料筒温度。料筒温度的选择对PBT的成型十分重要,如温度过低,塑化不良,会造成制品缺料、凹陷,收缩不均和无光泽等现象。而温度过高,会造成喷嘴流涎严重,溢边,色泽变深,甚至降解。通常,料筒温度控制在240~280℃,玻纤增强PBT控制在230~260℃。而喷嘴温度应控制在低于料筒前段温度5~10℃。
2)模具温度。模温与制品的尺寸稳定性、翘曲变形、成型周期和结晶度有直接关系。PBT易于结晶,即使在常温下结晶也很快,故模具温度不需要太高,通常为40~60℃,而玻纤增强PBT的模温稍高,通常为60~80℃。
3)注射压力。PBT熔体粘度低,流动性好,可采用中等程度的注射压力,一般为60~90MPa,玻纤增强PBT为80~100MPa,通常注射压力随塑件厚度的增加而加大,但不要超过100MPa,否则会使脱模困难。
部分型号部分物性表
PP (polypropylene # folding glue | soft /BTS-G/ Mitsui toatsu)
Use: other
Characteristic notes: cold resistance, impact resistance
Important beters: melt flow rate: 1.5 g/10min
Manufacturer: Mitsui East Pressure Chemical Corporation
PP (polypropylene # folding glue | soft /BJS-MF/ Mitsui toatsu)
Use: other
Important beters:
Manufacturer: Mitsui East Pressure Chemical Corporation
PP (polypropylene # folding glue | soft) /EPT30R/ Dushanzi petrochemical
Use: other
Important beters: melt flow rate: 3.5 g/10min notch impact strength: 98 thermal debation temperature: 80 C
Manufacturer: Dushanzi Petrochemical General Plant
PP (polypropylene # folding glue | soft /F500/ langang petrochemical)
Use: film grade
Important beters: melt flow rate: 3.2 g/10min tensile strength: 32.4 MPa VEKA softening point: 150 C
Manufacturer: Gansu langang Petrochemical Co., Ltd.
PP (polypropylene # folding glue | soft /KS607/ America Ineos)
Use: film grade
Important beters: melt flow rate: 5 g/10min density: 0.895 g/cm3, tensile strength: 27 MPa flexural modulus: 850 MPa hardness: 65 VEKA softening point: 129 DEG heat debation temperature: 70 C.
Manufacturer: America Ineos
PP (polypropylene # folding glue | soft chemical /TE-5102/LG)
Use: other
Important beters: density: 1.03 g/cm3, molding shrinkage: 1.1%, tensile strength: 17 MPa, elongation at break: 300% flexural strength: 20 MPa, bending modulus: 105 MPa, hot debation temperature: 99 degrees.
Manufacturer: Korea LG chemical company
PP (polypropylene # folding glue | soft /TI4130G/ Sunoco America)
Use: other
Characteristic note: medium impact
Important beters: melt flow rate: 13 g/10min notch impact strength: 107 tensile strength: 25 MPa fracture elongation: 8.5% flexural modulus: 1103 MPa hardness: 80
Manufacturer: Sunoco company, USA
PP (polypropylene # folding glue | soft chemical /HM-4354/LG)
Use: other
Important beters: density: 1.18 g/cm3 notch impact strength: 40 tensile strength: 44 MPa fracture elongation: 7% bending strength: 77 MPa flexural modulus: 421 MPa
Manufacturer: Korea LG chemical company
PP (polypropylene # folding glue | soft chemical /LW-4302/LG)
Use: other
Important beters: density: 1.21 g/cm3, molding shrinkage: 0.4% notched impact strength: 120 tensile strength: 69 MPa, elongation at break: 5% bending strength: 98 MPa flexural modulus: 411 MPa
Manufacturer: Korea LG chemical company
PP (polypropylene # folding glue | soft) /HP561S/ Basel
Use: other
Characteristic notes: suitable for extrusion applications
Important beters: melt flow rate: 33 g/10min tensile strength: 35 MPa elongation at break: 50% bending modulus: 1625 MPa VEKA softening point: 152 DEG heat: 86 C.
Manufacturer: Basel company
PP (polypropylene # folding glue | soft /M9600/ Lotte chemical)
Use: film grade
Important beters: melt flow rate: 25 g/10min density: 0.9 g/cm3, notched impact strength: 95 tensile strength: 29 MPa, elongation at break: 500% VEKA softening point: 150 DEG heat debing temperature: 104 C.
Manufacturer: Korean Music Corporation
PP (polypropylene # folding glue | soft) /100-NA70/BP
Use: other
Characteristic notes: high speed molding
Important beters: melt flow rate: 70 g/10min notch impact strength: 2.5 tensile strength: 36 MPa flexural modulus: 1700 MPa thermal debation temperature: 110 C
Manufacturer: Amoco chemicals company
PP (polypropylene # folding glue | soft /SR-6D/ Mitsui toatsu)
Use: other
Characteristic notes: polyolefin composite resin
Important beters: melt flow rate: 10 g/10min
Manufacturer: Mitsui East Pressure Chemical Corporation
PP (polypropylene # folding glue | soft /BJS-M/ Mitsui toatsu)
Use: other
Feature remark: injection molding grade
Important beters: melt flow rate: 1.5 g/10min
Manufacturer: Mitsui East Pressure Chemical Corporation
PP (polypropylene # folding glue | soft) /JLT36F/ Ji'nan refinery
Use: other
Characteristic notes: film, wire drawing, injection molding
Important beters: melt flow rate: 2.75 g/10min tensile strength: 32.8 MPa
Manufacturer: Sinopec group Ji'nan refinery
PP (polypropylene # folding glue | soft) /H029SP/ India Xincheng
Use: other
Important beters: melt flow rate: 2.9 g/10min notched impact strength: 40 tensile strength: 36 MPa elongation at break: 8% bending modulus: 1650 MPa, hot debation temperature: 104 C.
Manufacturer: Reliance Industries Limited, India
PP (polypropylene # folding glue | soft) /H200MK/ India Xincheng
Use: other
Important beters: melt flow rate: 3.3 g/10min notched impact strength: 88 tensile strength: 35 MPa elongation at break: 4% bending modulus: 680 MPa, hot debation temperature: 110 C.
Manufacturer: Reliance Industries Limited, India
PP (polypropylene # folding glue | soft) /HP556H/ Basel
Use: other
Characteristic notes: extrusion stage
Important beters: melt flow rate: 1.7 g/10min tensile strength: 32 MPa elongation at break: 50% bending modulus: 1500 MPa VEKA softening point: 154 DEG heat: 85 C.
Manufacturer: Basel company
PP (polypropylene # folding glue | soft /TR3020C/ Sunoco America)
Use: other
Characteristic notes: high modulus
Important beters: melt flow rate: 2 g/10min notch impact strength: 64 tensile strength: 32 MPa fracture elongation: 12% flexural modulus: 1172 MPa
Manufacturer: Sunoco company, USA
PP (polypropylene # folding glue | soft /TR3020F/ Sunoco America)
Use: other
Characteristic notes: high modulus
Important beters: melt flow rate: 2 g/10min notch impact strength: 75 tensile strength: 29 MPa fracture elongation: 13% flexural modulus: 1069 MPa
Manufacturer: Sunoco company, USA

